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HomeMy WebLinkAboutAgenda Report - October 2, 2013 G-02 PHAGENDA ITEM';'*I CITY OF LODI COUNCIL COMMUNICATION • TM AGENDA TITLE: Public Hearing to Receive Comments on and Consider Accepting City of Lodi's Report on Water Quality Relative to Public Health Goals MEETING DATE: October 2, 2013 PREPARED BY: Public Works Director RECOMMENDED ACTION: Public hearing to receive comments on and consider accepting the City of Lodi's Report on Water Quality Relative to Public Health Goals. BACKGROUND INFORMATION: Our water system complies with all of the health -based drinking water standards and maximum contaminant levels as required by the California Department of Health Services and the United States Environmental Protection Agency. The attached report prepared by staff compares Lodi's drinking water with the California Environmental Protection Agency's public health goals (PHGs) and with the United States Environmental Protection Agency's maximum contaminant level goals (MCLGs). PHGs and MCLGs are not enforceable standards and no action to meet them is mandated. California Code of Regulations, Title 22, Section 116470, mandates that a report be prepared every three years. The attached report is intended to provide information to the public, in addition to the Annual Water Quality Report mailed to each customer in June 2013. On August 10, 2013, a public notice appeared in the Lodi News Sentinel to inform any interested party of the Public Health Goals Report and its availability. The report is also posted on the City's website. The law also requires that a public hearing be held (which can be part of a regularly -scheduled public meeting) for the purpose of accepting and responding to public comment on the report. A notice of public hearing will be published in the Lodi News Sentinel. No additional actions are required or recommended. FISCAL IMPACT: Not applicable FUNDING AVAILABLE: Not applicable. F. Wallyndelin Public Works Director Prepared by Larry Parlin, Deputy Public Works Director — Utilities FWS/LP/pmf Attachment cc: Deputy Public Works Director —Utilities Utilities Superintendent Water Plant Chief Operator Bartlam, qty Manager K:\WP\COUNCIL\2013\PH PublicHealthGoalsReport.doc 9/23/2013 CITY OF LODI PUBLIC WORKS DEPARTMENT PUBLIC W0RK0Q- Report on Water Quality Relative to Public Health Goals 2010-2012 September 2013 ' 1 PUBLIC W0RK0Q- Report on Water Quality Relative to Public Health Goals 2010-2012 September 2013 TABLE OF CONTENTS SECTION Page BACKGROUND...............................................................................;.......................I........, ......,......1 PUBLIC HEALTH GOALS.. ......... ...............................................I.................. .......................1 CITY OF LODI WATER SOURCES.................................,.................................................,.......1 WATER QUALITY DATA CONSIDERED .................................................................... ............1 GUIDELINES FOLLOWED......................................................................................................................2 BEST AVAILABLE TREATMENT TECHNOLOGY AND COST ESTIMATES ............................. 2 CONSTITUENTS DETECTED THAT EXCEED A PHG OR A MCLG............................................. 2 ColiformBacteria ................. ............................. ...............................................................2 Trichloroethylene....................................................................................................................... 3 Dibromochloropropane............................................................................................................. 3 1,1,2,2 -Tetrachloroethylene . ....................................................................................... .. .. 4 1,2,3-Trichloropropane.............................................................................................. ............4 Arsenic............... ................. ............................... ........ ............................. ......... 5 Radium226............................................................ ........................................................................5 Radium228 ..... ........ ................................................................................................ .............6 Uranium........................................................................................................... ..... ............... 6 RECOMMENDATIONS FOR FURTHER ACTION.,......................................................................... 7 Appendix Water Quality Table Relative to Public Health Goals Attachments 1. MCLs, DLRs and PHGs for Regulated Drinking Water Contaminants 2. Health Risk Information for Public Health Goal Exceedance Reports 3. Cost Estimates for Treatment Technologies Background Provisions of the California Health and Safety Code (Reference No. 1) specify that larger (>10,000 service connections) water utilities prepare a special report every three years if their water quality measurements have exceeded any Public Health Goals (PHGs). PHGs are non -enforceable goals established by the Cal -EPA's Office of Environmental Health Hazard Assessment (OEHHA). The law also requires that where OEHHA has not adopted a PHG for a constituent, the water suppliers are to use the Maximum Contaminant Level Goals (MCLGs) adopted by USEPA. Only constituents which have a California primary drinking water standard and for which either a PHG or MCLG has been set are to be addressed. There are a few constituents that are routinely detected in water systems at levels usually well below the drinking water standards for which no PHG nor MCLG has been adopted by OEHHA or USEPA. If a constituent was detected in the City's water supply between 2010 and 2012 at a level exceeding an applicable PHG or MCLG, this report provides the information required by law. Included is the numerical public health risk associated with the MCL and the PHG or MCLG, the category or type of risk to health associated with each constituent, the best available treatment technology that could be used to reduce the constituent level, and an estimate of the cost to implement that treatment if it is appropriate and feasible. What Are PHGs? PHGs are set by the California Office of Environmental Health Hazard Assessment (OEHHA) which is part of Cal -EPA, and are based solely on public health risk considerations. None of the practical risk -management factors that are considered by the USEPA or the California Department of Public Health (CDPH) in setting drinking water standards (MCLS) are considered in setting the PHGs. These factors include analytical detection capability, available treatment technology, benefit and cost. The PHGs are not enforceable and are not required to be met by any public water system. MCLGs are the federal equivalent to PHGs. City of Lodi Water Sources The City of Lodi's water supply consists of both groundwater and surface water sources. Approximately 70 percent of the water supplied to our customers originates from wells owned by the City and the remainder of the City's drinking water is treated surface water produced through the new Surface Water Treatment Facility (SWTF). Water Quality Data Considered All of the water quality data collected by our water system between 2010 and 2012 for purposes of determining compliance with drinking water standards was considered. This data was summarized in our 2010, 2011, and 2012 Annual Water Quality Reports which were mailed to all customers before July 1St each year. The triennial lead and copper monitoring for 2012 was deferred by CDPH to 2013 and is not included in this report. Water Quality Report Relative to PHG 1 of 7 September 2013 Guidelines Followed The Association of California Water Agencies (ACWA) formed a workgroup that prepared guidelines that were used in the preparation of this report. Best Available Treatment Technology and Cost Estimates Both the USEPA and CDPH adopt what are known as Best Available Technologies (BATs) which are the best known methods of reducing contaminant levels to the MCL. Costs can be estimated for implementing such technologies. Since many PHGs and all MCLGs are set much lower than the MCL, it is not always possible or feasible to determine what treatment is needed to further reduce a constituent down to or near the PHG or MCLG, many of which are set at zero. Estimating the costs to reduce a constituent to zero is difficult, if not impossible. It is not possible to verify by analytical means that the level has been lowered to zero. In some cases, installing treatment to further reduce very low levels of one constituent may have adverse effects on other aspects of water quality. Constituents Detected That Exceed a PHG or a MCLG The following is a discussion of constituents that were detected in one or more of our drinking water sources at levels above the PHG, or if no PHG, above the MCLG. Coliform Bacteria In 2010-12, we collected 3,141 samples from our distribution system for coliform analysis. Of these samples, 0.22% was positive for coliform bacteria. In 2010-12 a maximum of 3.4% (April 2011) of these samples were positive for one month. The MCL for coliform is 5% positive samples of all samples per month and the MCLG is zero. The reason for the coliform drinking water standard is to minimize the possibility of the water containing pathogens which are organisms that cause waterborne disease. Because coliform is only an indicator of the potential presence of pathogens, it is not possible to state a specific numerical health risk. While U.S. EPA normally sets MCLGs "at a level where no known or anticipated adverse effects on persons would occur" they indicate that they cannot do so with coliforms. Coliform bacteria are organisms that are found just about everywhere in nature and are not generally considered harmful. They are used as an indicator because of the ease for monitoring and analysis. If a positive sample is found, it indicates a potential problem that needs to be investigated and follow up sampling is done. It is not at all unusual for a system to have an occasional positive sample. It is difficult, if not impossible, to assure that a system will never get a positive sample. A further test that is performed on all total coliform positive results is for fecal coliform or E. coli. There were no positive fecal coliform or E. coli results in 20010-12. The City adds chlorine to all City water sources to assure that the water served is microbiologically safe. The chlorine residual levels are carefully controlled to provide the best health protection without causing the water to have undesirable taste and odor or increasing the disinfection byproduct level. This careful balance of treatment processes is essential to continue supplying our customers with safe drinking water. Water Quality Report Relative to PHG 2 of 7 September 2013 Trichloroethylene (TCE) The PHG for TCE is 1.7 micrograms per liter (µg/l, or parts per billion). The MCL or drinking water standard for TCE is 5 gg/L. We detected TCE at levels above the PHG but not exceeding the MCL in the discharge from 1 of the 26 City wells used in 2010-12. The average value for the City wells can be found in the Water Quality Report (Appendix). The category of health risk associated with TCE, and the reason that a drinking water standard was adopted for it, is that the people who drink water containing TCE above the MCL throughout their lifetime could theoretically experience an increased risk of getting cancer. CDPH says that "Drinking water which meets this standard (the MCL) is associated with little to none of this risk and should be considered safe with respect to TCE." (CDPH Blue Book of drinking water law and regulations, Section 64468.2, Title 22, CCR.) The Best Available Technology for TCE to lower the level below the MCL is either Granular Activated Carbon or Packed Tower Aeration. The estimated cost to install such a treatment system on one City well and enhance the capacity on one City well with an existing treatment system that would reliably reduce the TCE level to below 1.7 µg/L would be approximately $490,000 and require annual operation and maintenance costs of approximately $77,000 per year. This would result in an estimated increased cost to each customer of approximately $5 per year. Dibromochloropropane (DBCP) The PHG for DBCP is 1.7 nanograms per liter (ng/L or parts per trillion). The MCL for DBCP is 200 ng/L. We detected DBCP at levels not exceeding the MCL in the discharges from 12 of the 26 City wells used in 2010-12. City Well No. 6 was taken out of service and placed in standby (January 2012) when the average analysis exceeded the MCL. Since then, the City has taken necessary steps to add Granulated Activated Carbon (GAC) vessels for treatment. This treatment was funded by Lodi's settlement agreement with DBCP manufactures and construction of the new treatment is near completion. The average value for these City wells can be found in the Water Quality Report (Appendix). The category for health risk associated with DBCP, and the reason that a drinking water standard was adopted for it, is the people who drink water containing DBCP above the MCL throughout their lifetime could theoretically experience an increased risk of getting cancer. CDPH says that "Drinking water which meets this standard (the MCL) is associated with little to none of this risk and should be considered safe with respect to DBCP." (CDPH Blue Book of drinking water law and regulations, Section 64468.3, Title 22, CCR.) The numerical health risk for an MCLG of zero is zero. The Best Available Technology for DBCP to lower the level below the MCL is either Granular Activated Carbon or Packed Tower Aeration. To attempt to maintain the DBCP levels at zero, Granular Activated Carbon Treatment Systems with longer empty bed contact times and more frequent carbon change -outs would likely be required. Water Quality Report Relative to PHG 3 of 7 September 2013 The estimated cost to install such a treatment system on 12 City wells and enhance capacities on six City wells with existing treatment systems that would reliably reduce the DBCP level to zero would be approximately $5.4 million. The increased annual operation and maintenance costs would be approximately $797,000 per year. This would result in an estimated increased cost to each customer of approximately $42 per year. (Note: This increased cost may not be reimbursable under the terms of Lodi's settlement agreement with the DBCP manufacturers.) 1,1,2,2 -Tetrachloroethylene (PCE) The PHG for PCE is 0.06 micrograms per liter (gg/L or parts per billion). The MCL or drinking water standard for PCE is 5 µg/L. We detected PCE at levels not exceeding the MCL in the discharges from three of the 26 City wells used in 2010-12. The average value for these City wells can be found in the Water Quality Report (Appendix). The category of health risk associated with PCE, and the reason that a drinking water standard was adopted for it, is the people who drink water containing PCE above the MCL throughout their lifetime could theoretically experience an increased risk of getting cancer. CDPH says that "Drinking water which meets this standard (the MCL) is associated with little to none of this risk and should be considered safe with respect to PCE." (CDPH Blue Book of drinking water law and regulations, Section 64468.2, Title 22, CCR.) The Best Available Technology for PCE to lower the level below the MCL is either Granular Activated Carbon or Packed Tower Aeration. Since the PCE level in these three City wells is already below the MCL, a Granular Activated Carbon Treatment System with larger vessels would likely be required to attempt to keep PCE levels below the PHG. The estimated cost to install such a treatment system on three City wells that would reliably reduce the PCE level to the PHG of 0.06 gg/L would be approximately $1.5 million and require annual operation and maintenance costs of approximately $180,000 per year. This would result in an estimated increased cost to each customer of approximately $14 per year. 1,2,3-Trichloropropane (1,2,3 -TCP) The PHG for 1,2,3 -TCP is 0.0007 micrograms per liter (µg2 or parts per billion). There is no California or federal Maximum Contaminant Level (MCL) for 1,2,3 -TCP. The California Notification Level for 1,2,3 -TCP is set at 0.005 µg/L, the detection limit for the purposes of reporting Detectable Level Required (DLR). Notification levels are health -based advisory levels established by CDPH for chemicals in drinking water that lack MCLs. CDPH advises "If a chemical concentration is greater than its notification level in drinking water that is provided to consumers, CDPH recommends that the utility inform its customers and consumers about the presence of the chemical, and about health concerns associated with exposure to it". We detected 1,2,3 -TCP at levels exceeding the PHG in the source water from six of the 26 City wells used in 2010-12. The average value for these City wells can be found in the Water Quality Report (Appendix). Currently, there is no MCL for 1,2,3 -TCP. The category for health risk associated with 1,2,3 -TCP, and the reason that a drinking water standard (PHG) was adopted for it, is the people who drink Water Quality Report Relative to PHG 4 of 7 September 2013 water containing 1,2,3 -TCP throughout their lifetime could theoretically experience an increased risk of getting cancer. An estimate of the best approach for 1,2,3 -TCP removal in Lodi is not necessary at this time. Arsenic The PHG for Arsenic is 0.004 micrograms per Liter (µg/L or parts per billion). The MCL or drinking water standard for arsenic is 10 pg/L. There were arsenic levels detected at levels not exceeding the MCL in discharges from 26 of the 26 City wells and the water treatment plant used in 2010-12. The values for these water sources can be found in the Water Quality Report (Appendix). Arsenic is a naturally occurring element found in many types of rocks and soils. Leaching of these deposits is the primary source of arsenic in this area. Some people who drink water containing arsenic in excess of the MCL over many years may experience skin damage or circulatory system problems and may have an increased risk of getting cancer. The PHG of 0.004 µg/L for arsenic is far below the Detection Limit Requirement (DLR) of 2 µg/L for arsenic. The DLR is the level that can be reliably determined by current laboratory methods. The Best Available Treatment (BAT) for arsenic removal is dependent on the water chemistry of the source to be treated. While research into new methods of removing arsenic continues, the current recommendations include: • Activated Alumina • Coagulation / Filtration • Lime Softening • Reverse Osmosis All of the above -listed methods are expensive and have a concentrated residual, which requires safe disposal. An estimate of the best approach for arsenic removal in Lodi is not necessary at this time. Radium 226 The PHG for Radium 226 is 0.05 pCi/L and MCL for Radium 226 plus Radium 228 is 5 pCi/L. Testing for radium is not required unless the level of gross alpha particle activity detected exceeds 5 pCi/L. We detected Radium 226 at levels not exceeding the MCL in the discharges from two of the 26 City wells used in 2010-12. The average value for this City well can be found in the Water Quality Report (Appendix). The category of health risk associated with Radium 226 is carcinogenicity. People who drink water containing Radium 226 particles above the MCL throughout their lifetime could experience an increased risk of getting cancer. The numerical health risk for Radium 226 based on the PHG is 1 x 10-6. This means one excess cancer case per million population. The BAT to lower the level of Radium 226 below the MCL is reverse osmosis, although it is not known if the technology is feasible of achieving the PHG level of 0.06 pCi/L. The estimated annual cost to install and operate a reverse osmosis systems at all of the City's wells would be approximately $2.60 per 1,000 gallons of treated water, which includes annualized cost of construction plus operation and maintenance costs. This translates into an estimated additional Water Quality Report Relative to PHG 5 of 7 September 2013 annual cost of approximately $35 per service connection per year for the life of the treatment system. Radium 228 The PHG for Radium 228 is 0.019 pCi/L and MCL for Radium 226 plus Radium 228 is 5 pCi/L. Testing for radium is not required unless the level of gross alpha particle activity detected exceeds 5 pCi/L. We detected Radium 228 at levels not exceeding the MCL in the discharges from two of the 26 City wells used in 2010-12. The average value for this City well can be found in the Water Quality Table (Appendix D). The category of health risk associated with Radium 228 is carcinogenicity. People who drink water containing Radium 228 particles above the MCL throughout their lifetime could experience an increased risk of getting cancer. The numerical health risk for Radium 228 based on the PHG is 1 x 10-6. This means one excess cancer case per million population. The BAT to lower the level of Radium 228 below the MCL is reverse osmosis, although it is not known if the technology is feasible of achieving the PHG level of 0.019 pCi/L. The estimated annual cost to install and operate a reverse osmosis systems at all of the City's wells would be approximately $2.60 per 1,000 gallons of treated water, which includes annualized cost of construction plus operation and maintenance costs. This translates into an estimated additional annual cost of approximately $35 per service connection per year for the life of the treatment system. Uranium The PHG for Uranium is 0.43 picocuries per liter (pCi/L). The MCL or drinking water standard for Uranium is 20 pCi/L. There was Uranium detected at levels not exceeding the MCL in discharges from 15 of the 25 City wells used in 2010-12. The values for these water sources can be found in the Water Quality Report (Appendix). CDPH, which sets drinking water standards, has determined that total Uranium is a health concern at certain levels of exposure. This radiological constituent is a naturally occurring contaminant in some groundwater and surface water supplies. This constituent has been shown to cause cancer in laboratory animals such as rats and mice when the animals are exposed at high levels over their lifetimes. Constituents that cause cancer in laboratory animals also may increase the risk of cancer in humans who are exposed over long periods of time. BATs for removal of Uranium from drinking water are: Ion Exchange - Reverse Osmosis or Lime Softening. These methods are expensive and require disposal of a waste stream, which would contain concentrated radio nucleotides. The estimated cost to install such a treatment system on fifteen City wells that have historically exceeded the PHG which would reliably reduce the Uranium level to the PHG of 0.43 pCi/L would be approximately $19.6 million and require annual operation and maintenance at a cost of approximately $820,000 per year. This would result in an estimated increased cost for each customer of approximately $121 per year. Water Quality Report Relative to PHG 6 of 7 September 2013 Recommendations for Further Action The drinking water quality of the City of Lodi Public Water System meets all State of California, CDPH and U.S. EPA drinking water standards set to protect public health. To further reduce the levels of the constituent's identified in this report that are already below the Maximum Contaminant Levels established by the State and Federal government, additional costly treatment processes would be required. The effectiveness of the treatment processes to provide significant reductions in constituent levels at these already low values is uncertain. The theoretical health protection benefits of these further reductions are not clear and may not be quantifiable. Therefore, staff is not recommending further action at this time. This report was completed by City of Lodi Public Works Department staff. Any questions relating to this report should be directed to: Larry Parlin, Deputy Public Works Director, 1331 South Ham Lane, Lodi, CA, 95242 or call (209) 333-6800, extension 2661. Andrew Richle, Chief Plant Operator, 2001 West Turner Road, Lodi, CA, 95242 or call (209) 333-6800, extension 2690. Water Quality Report Relative to PHG 7 of 7 September 2013 Appendix Appendix City of Lodi Water Quality Report Relative to Public Health Goals Trichloroethylene (TCE) Result MCL PHG or (MCLG) Well,2 2 ug/L 5 ug/L 1.7 ug/L Dibromochloropropane (DBCP) Well 1R 56 ng/L 200 ng/L 17 ng/L Well 4R 37 ng/L 200 ng/L 17 ng/L Well 6R 476 ng/L 200 ng/L 17 ngfL Well 8 178 ng/L 200 ng/L 17 ng/L Well 13 50 ng/L 200 ng/L 17 ng/L Well 14 40 ng/L 200 ng/L 17 ng/L Well 16 30 ng/L 200 ng/L 17 ng/L Well 17 177 ng/L 200 ng/L 17 ng/L Well 19 100 ng/L 200 ng/L 17 ng/L Well 22 40 ng/L 200 ng/L 17 ng/L Well 23 20 ng/L 200 ng/L 17 ng/L Well 28 95 ng/L 2DO ng/L 17 ng/L Perchloroethylene (PCE) 4.0 pCiA 20 pCUL 0.43 pCi/L Well 6R 2.43 ug/L 6 ug/L 0,06 ug/L Well 8 0.66 ug/L 6 ug/L 0.06 ug/L Well 12 0.88 ug/L 6 ug/L 0.06 ug/L Arsenic 7.4 pCiA 20 pCUL 0.43 pCUL Well 1R 5.6 ug/L 10 ug/L 0.004 ugiL Well 2 3,4 ugiL 10 ug/L 0.004 ug/L Well 3R 5.0 ug/L 10 ug/L 0.004 ug/L Well 4R 4.0 ug/L 10 ug/L 0.004 ug/L Well 5 4.4 ug/L 10 ug/L 0.004 ug/L Well 6R 2.2 ug/L 10 ug/L 0.004 ug/L Well 7 4.5 ug/L 10 ug/L O.OD4 ug/L Well 9 3.7 ugiL 10 ug/L 0.004 ug/L Well 10C 4.3 ug/L 10 ug/L 0.004 ug/L Well 11 R 5,5 ug/L 10 ug/L 0,004 ugiL Well 12 3.6 ug/L 10 ugiL 0.004 ug/L Well 13 8.7 ug/L 10 ug/L 0.004 ug/L Well 14 3.6 ug/L 10 ug/L 0.004 ug/L Well 15 4.6 ug/L 10 ug/L 0,004 ug/L Well 16 3.3 ug/L 10 ug/L 0.004 ug/L Well 17 3.9 ug/L 10 ug/L 0,004 ug/L Well 18 2.4 ug/L 10 ug/L 0.004 ug/L Notes: 'MCL for Radium 226 plus 228 is 5.0 pCUL -Source Water Sample Arsenic (Cont) Result MCL PHG or (MCLG) Well 19 2.9 ug/L 10 ug/L 0.004 u91L Well 20 3.2 ug/L 10 ugiL 0.004 ug/L We1121 2.5 ugiL 10 ug/L 0.004 ugiL Well 22 2.4 ug/L 10 ug/L 0.004 ug/L Well 23 2.7 ug/L 10 ugiL 0.004 ug/L Well 24 6.1 ug/L 10 ug/L 0.004 ug/L Well 25 6.2 ug/L 10 ugiL 0.004 ug/L Well 26 9.1 ug/L 10 ug/L 0.004 ug/L Well 28 6.2 ug/L 10 ug/L 0,004 ug/L Surafce Water Plant 0.4 ug/L 10 ug/L 0.004 ug/L Uranium Well 2 4.0 pCiA 20 pCUL 0.43 pCi/L Well 6R 11.2 pCiA 20 pCUL 0.43 pGVL Well 8 12.5 pCVI 20 pCUL 0.43 pCUL Well 9 5.2 pCi/I 20 pCUL 0.43 pCUL Well 12 7.4 pCiA 20 pCUL 0.43 pCUL Well 13 1.5 pCill 20 pCUL 0.43 pCUL Well 14 4.0 pCiA 20 pCi/L 0.43 pCi/L Well 16 4.7 pCiA 20 pCUL 0.43 pCUL Well 17 4.5 pCiA 20 pCIIL 0.43 pCUL Well 19 4.6 pCiA 20 pQIL 0.43 pCUL Well 20 2,5 pCUI 20 pCUL 043 pCi/L Well 21 1.0 PCO 20 pCUL 0.43 pCUL Well 22 9.5 pCUI 20 pCi/L 0.43 pCUL Well 23 7.7 pCVI 20 pCi/L 0.43 pCUL Radium 226 Well 8 0.25 pCUL -5A pCUL 0.05 pCUL Well 20 0.05 pCUL -5.0 pCi/L 0.05 pCUL Radium 228 Well 8 0.075 pCUL -5.0 pCUL 0.019 pCi/L Well 20 0.116 pCUL -5.0 pCi/L 0.019 pCUL **1,2,3 Trichoropropane Well 6R 0,005 ug/L NIA 0.0007 ug/L Well 13 0.026 ug/L N/A 0.0007 ug/L Well 16 0.004 ug/L NIA 0.0007 ug/L Well 18 0:009 ug/L N/A 0.0007 ug/L Well 20 0.015 ug/L N/A 0.0007 ug/L Well 21 0.003 ug/L NIA 0.0007 uq& F., rq P., q IT"Tor, m ATTACHMENT No. 1 2013 PHG Triennial Report: Calendar Years 2010-2011-2012 This table includes: • CDPH's maximum contaminant levels (MCLs) • CDPH's detection limits for purposes of reporting (DLRs) •_ Public health nooals (PHGs) from the Office of Environmental Health Hazard Assessmgnt (OEHHAI • PHGs for NDMA and 1,2,3-Trichloropropane (1,2,3 -TCP is unregulated) are at the bottom of this table • The federal MCLG for chemicals without a PHG, microbial contaminants, and the DLR for 1,2,3 -TCP Constituent MCL DLR PHG or MCLG Date of PHG Chemicals with MCLs in 22 CCR §64431—Inorganic Chemicals Aluminum 1 0.05 0.6 2001 Antimony 0.006 0.006 0.02 1997 Arsenic 0.010 0.002 0.000004 2004 Asbestos (MFL = million fibers per liter; for fibers 7 MFL 0.2 MFL >10 microns Ion 7 MFL 2003 Barium 1 0.1 2 2003 Beryllium 0.004 0.001 0.001 2003 Cadmium 0.005 0,001 0.00004 2006 Chromium, Total - OEHHA withdrew the 1999 0.0025 m /L PHG in Nov 2001 0.05 0.01 (0.100) Chromium, Hexavalent (Chromium -6) - MCL to be established - currently regulated under the total — 0.001 chromium MCL 0.00002 2011 Cyanide 0.15 0.1 0.15 1997 Fluoride 2 0.1 1 1997 Mercury (inorganic) 0.002 0.001 0.0012 1999 (rev2005)* Nickel 0.1 0.01 0.012 2001 Nitrate (as NO3) 45 2 45 1997 Nitrite (as N) 1 as N 0.4 1 as N 1997 Nitrate + Nitrite 10 as N 0.4 10 as N 1997 Perchlorate 0.006 0.004 0.006 2004 Selenium 0.05 0.005 0.03 2010 Thallium 0,002 0.001 0.0001 1999 (rev2004) Copper and Lead, 22 CCR §64672.3 Values referred to as MCLs for lead and copper are not actually MCLs; instead, they are called 'Action Levels" under the lead and copper rule Copper 1.3 0.05 0.3 2008 Lead 0.015 0.005 0.0002 2009 1 of 4 ATTACHMENT No. 1 Constituent MCL DLR PHG or MCLG Date of PHG Radionuclides with MCLS in 22 CCR §64441 and §64443 -Radioactivity [units are picocuries per titer (pCi/L), unless otherwise stated; n/a = not applicable] Gross alpha particle activity - OEHHA concluded in 2003 that a PHG was not practical 15 3 (zero) We Gross beta particle activity - OEHHA concluded i 2003 that a PHG was not practical 4 mrem/yr 4 (zero) n/a Radium -226 - 1 0.05 2006 Radium -228 - 1 0.019 2006 Radium -226 + Radium -228 5 -- (zero) - Strontium -90 8 2 0.35 2006 Tritium 20,000 1,000 400 2006 Uranium 1 20 1 1 1 0.43 1 2001 Chemicals with MCLS in 22 CCR §64444 -Organic Chemicals (a) Volatile Organic Chemicals (VOCs) Benzene 0.001 0.0005 0.00015 2001 Carbon tetrachloride 0.0005 0.0005 0.0001 2000 1,2 -Dichlorobenzene 0.6 0.0005 0.6 1997 (rev2009) 1,4 -Dichlorobenzene (p -DCB) 0.005 0.0005 0.006 1997 1,1-D'ichloroethane (1,1 -DCA) 0.005 0.0005 0.003 2003 1,2-Dichloroethane (1,2 -DCA) 0.0005 0.0005 0.0004 1999 (rev2005) 1,1-Dichloroethylene (1,1-DCE) 0.006 0.0005 0.01 1999 cis-1,2-Dichloroethylene 0.006 0.0005 0.1 2006 trans-1,2-Dichloroethylene 0.01 0.0005 0.06 2006 Dichloromethane (Methylene chloride)_ 0.005 0.0005 0.004 2000 1,2-Dichloropropane 0.005 0.0005 0.0005 1999 1,3-Dichloropropene 0.0005 0.0005 0.0002 1999 (rev2006) Ethylbenzene 0.3 0.0005 0.3 1997 Methyl tertiary butyl ether (MTBE) 0.013 0.003 0,013 1999 Monochiorobenzene 0.07 0.0005 0.2 2003 Styrene 0.1 0.0005 0.0005 2010 1,1,2,2 -Tetrachloroethane 0.001 0.0005 0.0001 2003 Tetrachloroethylene (PCE) 0.005 0.0005 0.00006 2001 Toluene 0.15 0.0005 0.15 1999 1,2,4-Trichlorobenzene 0.005 0.0005 0.005 1999 1,1,1 -Trichloroethane (1,1,1 -TCA) 0.2 0.0005 1 2006 1,1,2 -Trichloroethane (1,1,2 -TCA) 0.005 0,0005 0.0003 2006 Trichloroethylene (TCE) 0.005 0.0005 0.0017 2009 Trichlorofluoromethane (Freon 11) 0.15 0.005 0.7 1997 1,1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) 1.2 0.01 4 1997 (rev2011) Vinyl chloride 1 0.0005 0.0005 0.00005 2000 Xylenes 1.75 0.0005 1.8 1997 2 of 4 ATTACHMENT No. 1 Constituent MCL DLR PHG or MCLG Date of PHO Chemicals with MCLS in 22 CCR §64444 -Organic Chemicals (b) Non -Volatile Synthetic Organic Chemicals (SOCs) Alachlor 0.002 0.001 0.004 1997 Atrazine 0.001 0.0005 0.00015 1999 Bentazon 0.018 0.002 0.2 1999 (rev2009) Benzo(a)pyrene 0.0002 0.0001 0.000007 2010 Carbofuran 0.018 0.005 0.0017 2000 Chlordane 0.0001 0.0001 0.00003 1997 (rev2006) Dalapon 0.2 0.01 0.79 1997 (rev2009) 1,2-Dibromo-3-ehloropropane (DBCP) 0.0002 0.00001 0.0000017 1999 2,4-Dichlorophenoxyacetic acid (2,4-D) 0.07 0.01 0.02 2009 Di(2-ethylhexyl)adipate 0.4 0.005 0.2 2003 Di(2-ethylhexyl)phthalate (DEHP) 0.004 0.003 0.012 1997 Dinoseb 0.007 0.002 0.014 1997 (rev2010) Diquat 0.02 0.004 0.015 2000 Endrin 0.002 0.0001 0.0018 1999 (rev2008) Endothal 0.1 0.045 0.58 1997 Ethylene dibromide (EDB) 0.00005 0.00002 0.00001 2003 Glyphosate 0.7 0.025 0.9 2007 Heptachlor 0.00001 0.00001 0.000008 1999 Heptachlor epoxide 0.00001 0.00001 0.000006 1999 Hexachlorobenzene 0.001 0.0005 0.00003 2003 Hexachlorocyclopentadiene 0.05 0.001 0.05 1999 Lindane 0.0002 0.0002 0.000032 1999 (rev2005) Methoxychlor 0.03 0.01 0.00009 2010 Molinate 0.02 0.002 0.001 2008 Oxamyl 0.05 0.02 0.026 2009 Pentachlorophenol 0.001 0.0002 0.0003 2009 Picloram 0.5 0.001 0.5 1997 Polychlorinated biphenyls (PCBs) 0.0005 0.0005 0.00009 2007 Simazine 0.004 0.001 0.004 2001 2,4,5 -TP (Silvex) 0.05 0.001 0.025 2003 2,3,7,8-TCDD (dioxin) 3x10' 5x10-9 5x10-11 2010 Thiobencarb 0.07 1 0.001 1 0.07 1 2000 Toxaphene 0.003 1 0.001 1 0.00003 1 2003 3 of 4 ATTACHMENT No. 1 Constituent MCL DLR or PHG MGLG Date of PHG Chemicals with MCLS in 22 CCR §64533—Disinfection Byproducts Total Trihalomethanes 0.080 -- -- Bromodichloromethane -- 0.0010 (zero) — Bromoform -- 0.0010 (zero) -- Chloroform _ -- 0.0010 (0.07) -- Dibromochloromethane -- 0.0010 (0.06) -- Haloacetic Acids five HAAS 0.060 -- -- -- Monochloroacetic Acid -- 0.0020 (0.07) — Dichloroacetic Adic -- 0.0010 (zero) Trichloroacetic Acid — 0.0010 (0.02) — Monobromoacetic Acid -- 0.0010 — -- Dibromoacetic Acid — 0.0010 Bromate 0.0050 or 0.010 0.0010a 0.0001 2009 Chlorite 1.0 0.020 0.05 2009 Microbiological Contaminants (TT = Treatment Technique) Coliform % positive samples % 5 (zero) Cryptosporidium** TT (zero) Giardia lamblia** TT (zero) Legionella** TT (zero) Viruses** TT (zero) Chemicals with PHGs established in response to CDPH requests. These are not currently regulated drinking water contaminants. N-Nitrosodimethylamine (NDMA) 1 0.000003 2006 1,2 3-Trichloro ro ane -- 0.000005 1 0.0000007 2009 Notes: a CDPH will maintain a 0.0050 mg/L DLR for bromate to accommodate laboratories that are using EPA Method 300.1. However, laboratories using EPA Methods 317.0 Revision 2.0, 321.8, or 326.0 must meet a 0.0010 mg/L MRL for bromate and should report results with a DLR of 0.0010 mg/L per Federal requirements. *OEHHA's review of this chemical during the year indicated (rev20XX) resulted in no change in the PHG ** Surface water treatment = TT 4 of 4 Attachment No. 2 Health Risk Information for Public Health Goal Exceedance Reports Prepared by Office of Environmental Health Hazard Assessment California Environmental Protection Agency February 2013 Under the Calderon -Sher Safe Drinking Water Act of 1996 (the Act), water utilities are required to prepare a report every three years for contaminants that exceed public health goals (PHGs) (Health and Safety Code Section 116470 (2)[b]). The numerical health risk for a contaminant is to be presented with the category of health risk, along with a plainly worded description of these terms. The cancer health risk is to be calculated at the PHG and at the California maximum contaminant level (MCL). This report is prepared by the Office of Environmental Health Hazard Assessment (OEHHA) to assist the water utilities in meeting their requirements. PHGs are concentrations of contaminants in drinking water that pose no significant health risk if consumed for a lifetime. PHGs are developed and published by OEHHA (Health and Safety Code Section 116365) using current risk assessment principles, practices and methods. Numerical health risks. Table 1 presents health risk categories and cancer risk values for chemical contaminants in drinking water that have PHGs. The Act requires that OEHHA publish PHGs based on health risk assessments using the most current scientific methods. As defined in statute, PHGs for non -carcinogenic chemicals in drinking water are set at a concentration "at which no known or anticipated adverse health effects will occur, with an adequate margin of safety." For carcinogens, PHGs are set at a concentration that "does not pose any significant risk to health." PHGs provide one basis for revising MCLs, along with cost and technological feasibility. OEHHA has been publishing PHGs since 1997 and the entire list published to date is shown in Table 1. Table 2 presents health risk information for contaminants that do not have PHGs but have state or federal regulatory standards. The Act requires that, for chemical contaminants with California MCLs that do not yet have PHGs, water utilities use the Attachment No. 2 federal maximum contaminant level goal (MCLG) for the purpose of complying with the requirement of public notification. MCLGs, like PHGs are strictly health based and include a margin of safety. One difference, however, is that the MCI -Gs for carcinogens are set at zero because the United States Environmental Protection Agency (U.S. EPA) assumes there is no absolutely safe level of exposure to them. PHGs, on the other hand, are set at a level considered to pose no significant risk of cancer; this is usually a no more than one -in -a -million excess cancer risk (1x10-6) level for a lifetime of exposure. In Table 2, the cancer risks shown are based on the U.S. EPA's evaluations. For more information on health risks: The adverse health effects for each chemical with a PHG are summarized in each PHG technical support document. These documents are available on the OEHHA Web site (http://www.oehha.ca.gov). Also, U.S. EPA has consumer and technical fact sheets on most of the chemicals having MCLs. For copies of the fact sheets, call the Safe Drinking Water Hotline at 1-800-426-4791, or explore the U.S. EPA Ground Water and Drinking Water web page at http://water.epa.gov/drink/. Attachment No. 2 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) Based on the OEHHA PHG technical support document unless otherwise specified. The categories are the hazard traits defined by OEHHA for California's Toxics Information Clearinghouse (online at: httn://oehha.ca.gov/Multimediatoreen/od`f/GC ResatextO11912.adf1. mg1L = milligrams per liter of water or parts per million (ppm) S Cancer Risk = Upper estimate of excess cancer risk from lifetime exposure. Actual cancer risk may be lower or zero: 1x10.5 means one excess cancer case per million people exposed. 4 MCL = maximum contaminant level. 5 NA = not applicable. Risk cannot be calculated. The PHG is set at a level that is believed to be without any significant public health risk to individuals exposed to the chemical over a lifetime. 5 MFL = million fibers per liter of water. California Cancer California Cancer Chemical Health Risk Category' PHG Risk MCL4 Risk at the (mg/L)2 at the (mg/L) California PHG MCL Alachlor carcinogenicity 0.004 NA -5 0.002 NA (causes cancer) Aluminum neurotoxicity and 0.6 NA 1 NA immunotoxicity (harms the nervous and immune systems) Antimony digestive system toxicity 0.02 NA 0.006 NA (causes vomiting) Arsenic carcinogenicity 0.000004 1 x10.6 0.01 2.5x10-3 (causes cancer) (4x10-6) (one per (2.5 per million) thousand) Asbestos carcinogenicity 7 MFL6 1x10-6 7 MFL 1x10 (causes cancer) (fibers (fibers (one per >10 >10 million) microns in microns in length) length) Atrazine carcinogenicity 0.00015 1A0-6 0.001 7x10-6 (causes cancer) (seven per million) Based on the OEHHA PHG technical support document unless otherwise specified. The categories are the hazard traits defined by OEHHA for California's Toxics Information Clearinghouse (online at: httn://oehha.ca.gov/Multimediatoreen/od`f/GC ResatextO11912.adf1. mg1L = milligrams per liter of water or parts per million (ppm) S Cancer Risk = Upper estimate of excess cancer risk from lifetime exposure. Actual cancer risk may be lower or zero: 1x10.5 means one excess cancer case per million people exposed. 4 MCL = maximum contaminant level. 5 NA = not applicable. Risk cannot be calculated. The PHG is set at a level that is believed to be without any significant public health risk to individuals exposed to the chemical over a lifetime. 5 MFL = million fibers per liter of water. Attachment No. 2 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) Body weight effects are an indicator of general toxicity in animal studies. California Cancer California Cancer Chemical Health Risk Category' PHG Risk 3 MCL4 Risk at the (mg/L)z at the (mg/L) California PHG MCL Barium cardiovascular toxicity 2 NA 1 NA (causes high blood pressure) Bentazon hepatotoxicity and 0.2 NA 0.018 NA digestive system toxicity (harms the fiver, intestine, and causes body weight effects') Benzene carcinogenicity 0.00015 1x10"6 0.001 7x10"6 (causes leukemia) (seven per million) Benzofalpyrene carcinogenicity 0.000007 1x10"6 0.0002 3x10"5 (causes cancer) (three per hundred thousand) Beryllium digestive system toxicity 0.001 NA 0.004 NA (harms the stomach or intestine) Bromate carcinogenicity 0.0001 1x10-6 0.01 1x10-4 (causes cancer) (one per ten thousand) Cadmium nephrotoxicity 0.00004 NA 0.005 NA (harms the kidney) Carbofuran reproductive toxicity 0.0017 NA 0.018 NA (harms the testis) Body weight effects are an indicator of general toxicity in animal studies. Attachment No. 2 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) e AL = action level. The action levels for copper and lead refer to a concentration measured at the tap. Much of the copper and lead in drinking water is derived from household plumbing (The Lead and Copper Rule, Title 22, CaliforniaCode of Regulations [CCR] section 64672.3). California Cancer California Cancer Chemical Health Risk Category' PHG Risk MCL4 Risk at the (mg/L)2 at the (mg/L) California PHG MCL Carbon carcinogenicity 0.0001 1x10"6 0.0005 5x10-6 tetrachloride (causes cancer) (five per million) Chlordane carcinogenicity 0.00003 1x10-6 0.0001 3x10-6 (causes cancer) (three per million) Chlorite hematotoxicity 0.05 NA 1 NA (causes anemia) neurotoxicity (causes neurobehavioral effects) Chromium, carcinogenicity 0.00002 1x10-6 NA hexavalent (causes cancer) Copper digestive system toxicity 0.3 NA 1.3 (AL)' NA (causes nausea, vomiting, diarrhea) Cyanide neurotoxicity 0.15 NA 0.15 NA (damages nerves) endocrine toxicity (affects the thyroid) Dalapon nephrotoxicity 0.79 NA 0.2 NA (harms the kidney) 1_;2-Dibromo-3- carcinogenicity 0.0000017 1x10-6 0.0002 1x10-4 chloropropane (causes cancer) (1.7x10-6) (one per D( BCP) ten thousand) e AL = action level. The action levels for copper and lead refer to a concentration measured at the tap. Much of the copper and lead in drinking water is derived from household plumbing (The Lead and Copper Rule, Title 22, CaliforniaCode of Regulations [CCR] section 64672.3). Attachment No. 2 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) California Cancer California Cancer Chemical Health Risk Category' PHG Risk MCL4 Risk at the (mg/L)2 at the (mg/L) California PHG MCL 1,2-Dichloro- hepatotoxicity 0.6 NA 0.6 NA benzene (o- (harms the liver) DCB) 1,4-Dichloro- carcinogenicity 0.006 1x10-6 0.005 8x10-7 benzene (p- (causes cancer) (eight per DCB) ten million) 1.1-Dichloro- carcinogenicity 0.003 1x10-6 0.005 2x10-6 ethane [1_,'I- (causes cancer) (two per DCA) million) 1.2-Dichloro- carcinogenicity 0.0004 1x10-6 0.0005 1x10-6 ethane (1,2- (causes cancer) (one per DCA) million) 1.1-Dichloro- hepatotoxicity 0.01 NA 0.006 NA ethylene (harms the liver) (1, 1-DCE) 1,2-Dichloro- nephrotoxicity 0.1 NA 0.006 NA ethylene, cis (harms the kidney) 1,2-Dichloro- hepatotoxicity 0.06 NA 0.01 NA ethylene, trans (harms the liver) Dichloromethane carcinogenicity (causes cancer) 0.004 1x10-6 0.005 1x10-6 (one per (methylene chloride) million) 2,4-Dichloro- hepatotoxicity and 0.02 NA 0.07 NA phenoxyacetic nephrotoxicity acid (2,4-D) (harms the liver and kidney) Attachment No. 2 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) California Cancer California Cancer Chemical Health Risk Category' PHG Risk' MCL4 Risk at the (mg/L)2 at the (mg/L) California PHG MCL 1,2-Dichloro- carcinogenicity 0.0005 1x10-6 0.005 1x10-5 propane (causes cancer) (one per (progylene hundred dichloride` thousand.) 1.3-Dichloro- carcinogenicity 0.0002 1x10.6 0.0005 2x10"6 propene (causes cancer) (two per (Telone II®) million) Di(2-ethylhexyl) developmental toxicity 0.2 NA 0.4 NA adipate (DEHA) (disrupts development) Diethylhexyl- carcinogenicity 0.012 1x10"6 0.004 3x10"' phthalate (causes cancer) (three per D( EHP) ten million) Dinoseb reproductive toxicity 0.014 NA 0.007 NA (harms the uterus and testis) Dioxin (2,37,8- carcinogenicity 5x10-' 1x10 3x10-$ 6x10 TCDD) (causes cancer) (six per ten thousand) Di uat ocular toxicity 0.015 NA 0.02 NA (harms the eye) developmental toxicity (causes malformation) Endothall digestive system toxicity 0.58 NA 0.1 NA (harms the stomach or intestine) Endrin hepatotoxicity 0.0018 NA 0.002 NA (harms the liver) neurotoxicity (causes convulsions) Attachment No. 2 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) California Cancer California Cancer Chemical Health Risk Category' PHG Risk MCL4 Risk at the (mg/L)Z at the (mg/L) California PHG MCL Ethylbenzene hepatotoxicity 0.3 NA 0.3 NA (phenylethane) (harms the liver) Ethylene carcinogenicity 0.00001 1x10.6 0.00005 5x10"6 dibromide (causes cancer) (five per million) Fluoride musculoskeletal toxicity 1 NA 2 NA (causes tooth mottling) Glyphosate nephrotoxicity 0.9 NA 0.7 NA (harms the kidney) Heptachlor carcinogenicity 0.000008 1x10-6 0.00001 1x10-6 (causes cancer) (one per million) Heptachlor carcinogenicity 0.000006 1x10-6 0.00001 2x10-6 epoxide (causes cancer) (two per million) Hexachloroben- carcinogenicity 0.00003 1x10'6 0.001 3x10"5 zene (causes cancer) (three per hundred thousand) Hexachloro- digestive system toxicity 0.05 NA 0.05 NA cvclopentadiene (causes stomach lesions) (HEX) Attachment No. 2 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) California Cancer California Cancer Chemical Health Risk Category' PHG Risk MCL4 Risk at the (mg/L)Z at the (mg/L) California PHG MCL Lead developmental 0.0002 3x10-8 0.015 2x10"6 neurotoxicity (PHG is (AL)8 (two per (causes neurobehavioral not based million) effects in children) on this cardiovascular toxicity effect) (cause high blood pressure) carcinogenicity (causes cancer) Lindane carcinogenicity 0.000032 1x10-6 0.0002 6x10 (Y -BHC) (causes cancer) (six per million) Mercury nephrotoxicity 0.0012 NA 0.002 NA inor anic (harms the kidney) Methoxychlor endocrine toxicity 0.00009 NA 0.03 NA (causes hormone effects) Methyl tertiary- carcinogenicity 0.013 1 x 10`6 0.013 1 x 10-6 butyl ether (causes cancer) (one per MTBE million) Molinate carcinogenicity 0.001 1x10'6 0.02 2x10-5 (causes cancer) (two per hundred thousand) Monochloro- hepatotoxicity 0.2 NA 0.07 NA benzene (harms the liver) (chlorobenzene) Nickel developmental toxicity 0.012 NA 0.1 NA (causes increased neonatal deaths) Attachment No. 2 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) 9 This is the current PHG value for perchlorate. A revised draft PHG for perchlorate was posted online for public comment on December 7, 2012. htt2://www.oehha.ce.aov/water/nho/120712Perchlorate.htmi. California Cancer California Cancer Chemical Health Risk Category' PHG Risk MCL4 Risk at the (mg/L)2 at the (mg/L) California PHG MCL Nitrate hematotoxicity 45 as NA 45 as NO3 NA (causes nitrate methemoglobinemia) Nitrite hematotoxicity 1 as NA 1 as NA (causes nitrogen nitrite- methemoglobinemia) nitrogen Nitrate and hematotoxicity 10 as NA 10 as NA Nitrite (causes nitrogen nitrogen methemoglobinemia) N -nitroso- carcinogenicity 0.000003 1x10-6 -- NA dimethyl -amine (causes cancer) N( DMA) Oxamyl general toxicity 0.026 NA 0.05 NA (causes body weight effects) Pentachloro- carcinogenicity 0.0003 1x10 0.001 3x10-6 phenol (PCP) (causes cancer) (three per million) Perchlorate endocrine toxicity 0.006' NA 0.006 NA (affects the thyroid) developmental toxicity (causes neurodevelop- mental deficits) Picloram hepatotoxicity 0.5 NA 0.5 NA (harms the liver) 9 This is the current PHG value for perchlorate. A revised draft PHG for perchlorate was posted online for public comment on December 7, 2012. htt2://www.oehha.ce.aov/water/nho/120712Perchlorate.htmi. Attachment No. 2 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) California Cancer California Cancer Chemical Health Risk Category' PHG Risk MCL4 Risk at the (mg/L)2 at the (mg/L) California PHG MCL Polychlorinated carcinogenicity 0.00009 1x10-6 0.0005 6x10-6 biphenyls (causes cancer) (six per (PCBs) million) Radium -226 carcinogenicity 0.05 pCi/L 1x10-6 5 pCi/L 1x10 (causes cancer) (one per ten thousand) Radium -228 carcinogenicity 0.019 pCi/L 1x10-6 5 pCi/L 3x10 (causes cancer) (combined (three per Ra226+228) ten thousand) Selenium integumentary toxicity 0.03 NA 0.05 NA (causes hair loss and nail damage) Silvex (2,4,5 -TP) hepatotoxicity (harms the liver) 0.025 NA 0.05 NA Simazine general toxicity 0.004 NA 0.004 NA (causes body weight effects) Strontium -90 carcinogenicity 0.35 pCi/L 1x10-6 8 pCi/L 2x10-5 (causes cancer) (two per hundred thousand) Styrene carcinogenicity 0.0005 1x10-6 0.1 2x10-4 (vinylbenzene) (causes cancer) (two per ten thousand) Attachment No. 2 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) California Cancer California Cancer Chemical Health Risk Category' PHG Risk MCL4 Risk at the (mg/L)2 at the (mg/L) California PHG MCL 1,1,2,2- carcinogenicity 0.0001 1x10'6 0.001 1x10-5 Tetrachloro- (causes cancer) (one per ethane hundred thousand) Tetrachloro- carcinogenicity 0.00006 1x10-6 0.005 8x10-5 ethylene (causes cancer) (eight per erch oro- hundred ethylene, or thousand) EgEj Thallium integumentary toxicity 0.0001 NA 0.002 NA (causes hair loss) Thiobencarb general toxicity 0.07 NA 0.07 NA (causes body weight effects) hematotoxicity affects red blood cells Toluene hepatotoxicity 0.15 NA 0.15 NA (methylbenzene) (harms the liver) endocrine toxicity (harms the thymus) Toxaphene carcinogenicity 0.00003 1x10-6 0.003 1x10-4 (causes cancer) (one per ten thousand) 1.2;4-Trichloro- endocrine toxicity 0.005 NA 0.005 NA benzene (harms adrenal glands) .(Unsym-TCB) Attachment No. 2 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) California Cancer California Cancer Chemical Health Risk Category' PHG Risk MCL4 Risk at the (mg/L)2 at the (mg/L) California PHG MCL 1,1,1-Trichloro- neurotoxicity 1 NA 0.2 NA ethane (harms the nervous system), reproductive toxicity (causes fewer offspring) hepatotoxicity (harms the Liver) hematotoxicity causes blood effects 1.1.2-Trichloro- carcinogenicity 0.0003 1x10"6 0.005 2x10-5 ethane (causes cancer) (two per hundred thousand) 112-Trichloro- carcinogenicity 0.0017 1x10'6 0.005 3x10"6 ethylene (TCE) (causes cancer) (three per million) Trichlorofluoro- hepatotoxicity 0.7 NA 0.15 NA methane (harms the liver) Freon 11 1,2,3-Trichloro- carcinogenicity 0.0000007 1x10"6 -- NA propane (causes cancer) (1,2,3 -TCP) 1,1,2-Trichloro- hepatotoxicity 4 NA 1.2 NA 1,2,2-trifluoro- (harms the liver) ethane (Freon 113) Tritium carcinogenicity 400 pCi/L 1 x10-6 20,000 5x10-5 (causes cancer) pCi/L (five per hundred thousand) Attachment No. 2 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) California Cancer California Cancer Chemical Health Risk Category' PHG Risk MCL4 Risk at the (mg/L)2 at the (mglL) California PHG MCL Uranium carcinogenicity 0.43 pCi/L 1x10 20 pCi/L 5x10`5 (causes cancer) (five per hundred thousand) Vinyl chloride carcinogenicity 0.00005 1x10"6 0.0005 1x10-5 (causes cancer) (one per hundred thousand) Xylene neurotoxicity 1.8 (single NA 1.75 (single NA (affects the senses, isomer or isomer or mood, and motor sum of sum of control) isomers) isomers) Attachment No. 2 Table 2: Health Risk Categories and Cancer Risk Values for Chemicals without California Public Health Goals Health risk category based on the U.S. EPA MCLG document or California MCL document unless otherwise specified. 2 MCLG = maximum contaminant level goal established by U.S. EPA. s Cancer Risk =Upper estimate of excess cancer risk from lifetime exposure. Actual cancer risk maybe lower or zero. 1 x10-6 means one excess cancer case per million people exposed. 4 California MCL = maximum contaminant level established by California.. 5 Maximum Residual Disinfectant Level Goal, or MRDLG 6 Body weight effects are an indicator of general toxicity in animal studies. U.S. EPA Cancer California Cancer Chemical Health Risk Category' MCLG2 Risk MCL 4 Risk @ (mg/L) @ (mg/L) California MCLG MCL Disinfection byproducts (DBPS) Chloramines acute toxicity 45 NA none NA (causes irritation) digestive system toxicity (harms the stomach) hematotoxicity causes anemia Chlorine acute toxicity 45 NA none NA (causes irritation) digestive system toxicity harms the stomach Chlorine dioxide hematotoxicity 0.85 NA none NA (causes anemia) neurotoxicity (harms the nervous system) Disinfection byproducts: haloacetic acids (HAAS) Chloroacetic acid general toxicity 0.07 NA none NA (causes body and organ weight changes6) Dichloroacetic carcinogenicity 0 0 none NA acid (causes cancer) Trichloroacetic hepatotoxicity 0.02 0 none NA acid (harms the liver) Bromoacetic acid NA none NA none NA Health risk category based on the U.S. EPA MCLG document or California MCL document unless otherwise specified. 2 MCLG = maximum contaminant level goal established by U.S. EPA. s Cancer Risk =Upper estimate of excess cancer risk from lifetime exposure. Actual cancer risk maybe lower or zero. 1 x10-6 means one excess cancer case per million people exposed. 4 California MCL = maximum contaminant level established by California.. 5 Maximum Residual Disinfectant Level Goal, or MRDLG 6 Body weight effects are an indicator of general toxicity in animal studies. Attachment No. 2 Table 2: Health Risk Categories and Cancer Risk Values for Chemicals without California Public Health Goals Table 2: Health Risk Categories and Cancer Risk Values for Chemicals without California Public Health Goals U.S. EPA Cancer California Cancer Chemical Health Risk Category MCLG2 Risk MCL4 Risk @ (mg/L) @ (mg/L) California MCLG MCL Dibromoacetic NA none NA none NA acid Total haloacetic carcinogenicity none NA 0.06 NA acids (causes cancer) Disinfection byproducts: trihalomethanes (THMs) Bromodichloro- carcinogenicity 0 0 none NA methane (BDCM) (causes cancer) Bromoform carcinogenicity 0 0 none NA (causes cancer) Chloroform hepatotoxicity and 0.07 NA none NA nephrotoxicity (harms the liver and kidney) Dibromo- hepatotoxicity, 0.06 NA none NA chloromethane nephrotoxicity, and (DBCM) neurotoxicity (harms the liver, kidney, and nervous system) Total (sum of carcinogenicity none NA 0.08 NA BDCM, (causes cancer), bromoform, hepatotoxicity, chloroform and nephrotoxicity, and DBCM) neurotoxicity (harms the liver, kidney, and nervous system) Table 2: Health Risk Categories and Cancer Risk Values for Chemicals without California Public Health Goals Attachment No. 2 ' MCLs for gross alpha and beta particles are screening standards for a group of radionuclides. Corresponding PHGs were not developed for gross alpha and beta particles. See the OEHHA memoranda discussing the cancer risks at these MCLS at http://www.oehha.ca.gov/water/phglindex.htmi. 8 pCi/L = picocuries per liter of water. U.S. EPA Cancer California Cancer Chemical Health Risk Category' MCLG2 Risk' MCL4 Risk @ (mg/L) @ (mglL) California MCLG MCL Radionuclides Gross alpha carcinogenicity 0 (210Po 0 15 pCi/LB up to 1x10-3 particles (causes cancer) included) (includes �26Ra (for 210Po, but the most not radon potent and alpha uranium) emitter Beta particles and carcinogenicity o(21 Oft 0 50 pCi/L up to 2x10"3 photon emitters' (causes cancer) included) (judged (for 21 'Pb, equiv. to 4 the most mrem/yr) potent beta - emitter) ' MCLs for gross alpha and beta particles are screening standards for a group of radionuclides. Corresponding PHGs were not developed for gross alpha and beta particles. See the OEHHA memoranda discussing the cancer risks at these MCLS at http://www.oehha.ca.gov/water/phglindex.htmi. 8 pCi/L = picocuries per liter of water. ATTACHMENT NO. 3 Table 1 Reference: 2012 ACWA PHG Survey COST ESTIMATES FOR TREATMENTTECHNOLOGIES (INCLUDES ANNUALIZED CAPITAL AND O&M COSTS) Page 1 of 2 Estimated Unit Cost No. Treatment Source of Information 2012 ACWA Survey Technology ($/1,000 gallons treated 1 [on Exchange Coachella Valley WD, for GW, to reduce Arsenic concentrations. 1.84 2011 costs. 2 Ion Exchange City of Riverside Public Utilities, for GW, for Perchlorate treatment. 0.89 Carollo Engineers, anonymous utility, 2012 costs for treating GW source for Nitrates. Design souce water concentration: 88 mg/L NO3 3 Ion Exchange Design finished water concentration: 45 mg/L NO3. Does not include 0.67 concentrate disposal or land cost. 4 Granular City of Riverside Public Utilities, GW sources, for TCE, DBCP (VOC, 0.45 Activated Carbon SOC) treatment.. Carollo Engineers, anonymous utility, 2012 costs for treating SW 5 Granular source for TTHMs. Design souce water concentration: 0.135 mg/L. 0.32 Activated Carbon Design finished water concentration: 0.07 mg/L. Does not include concentrate disposal or land cost. 6 Granular Activated Carbon, LADWP, Liquid Phase GAC treatment at Tujunga Well field. Costs for 1.36 Liquid Phase treating 2 wells. Treament for 1,1 DCE (VOC). 2011-2012 costs. Carollo Engineers, anonymous utility, 2012 costs for treating GW source for Nitrates. Design souce water concentration: 88 mg/L NO3, 7 Reverse Osmosis Design finished water concentration: 45 mg/L NO3. Does not include 0'72 concentrate disposal or land cost. 8 Packed Tower City of Monrovia, treatment to reduce TCE, PCE concentrations. 2011 0.39 Aeration 12 costs. Ozonation+ SCVWD, STWTP treatment plant includes chemical addition + ozone 9 Chemical addition generation costs to reduce THM/HAAs concentrations. 2009-2012 0.08 costs. Ozonation+ SCVW D, PWTP treatment plant includes chemical addition + ozone 10 Chemical addition generation costs to reduce THM/HAAs concentrations, 2009-2012 0.18 costs. Page 1 of 2 COST ESTIMATES FOR TREATMENT TECHNOLOGIES (INCLUDES ANNUALIZED CAPITAL AND O&M COSTS) Page 2 of 2 Estimated Unit Cost No. Treatment Source of Information 2012 ACWA Survey Technology ($/1,000 gallons treated 11 Coagulation/Filtrat Soquel WD, treatment to reduce manganese concentrations in GW. 0.68 ion 2011 costs. Coagulation/Filtrat San Diego WA, costs to reduce THM/Bromate, Turbidity 12 ion Optimization concentrations, raw SW a blend of State Water Project water and 0.77 Colorado River water, treated at Twin Oaks Valley WTP. 13 Blending (Well) Rancho California WD, GW blending well, 1150 gpm, to reduce 0.64 fluoride concentrations. 14 Blending (Wells) Rancho California WD, GW blending wells, to reduce arsenic 0.52 concentrations, 2012 costs. 15 Blending Rancho California WD, using MWD water to blend with GW to reduce 0.62 arsenic concentrations. 2012 costs. 16 Corrosion Atascadero Mutual WC, corrosion inhibitor addition to control 0.08 Inhibition aggressive water. 2011 costs. Page 2 of 2 Please immediately confirm receipt of this fax by calling 333-6702 CITY OF LODI P. O. BOX 3006 LODI, CALIFORNIA 95241-1910 ADVERTISING INSTRUCTIONS SUBJECT: PUBLIC HEARING TO RECEIVE COMMENTS ON AND CONSIDER ACCEPTING CITY OF LODI'S REPORT ON WATER QUALITY RELATIVE TO PUBLIC HEALTH GOALS PUBLISH DATE: SATURDAY, SEPTEMBER 7, 2013 TEAR SHEETS WANTED: One (1) please SEND AFFIDAVIT AND BILL TO: RANDI JOHL-OLSON, CITY CLERK LNS ACCT. #0510052 City of Lodi P.O. Box 3006 Lodi, CA 95241-1910 DATED: THURSDAY, SEPTEMBER 5, 2013 ORDERED BY: RANDI JOHL-OLSON CITY CLERK NIFER . ROBISON, CMC SSISTAN CITY CLERK MARIA DITMORE ADMINISTRATIVE CLERK Faxed to the Sentinel at.369-1084 a' L.: (time) on (date) (pages) LNS Phoned to confirm receipt of all pages at" (time) MD JMR (initials) fortnAadvins.doc DECLARATION OF POSTING PUBLIC HEARING TO RECEIVE COMMENTS ON AND CONSIDER ACCEPTING CITY OF LODI'S REPORT ON WATER QUALITY RELATIVE TO PUBLIC HEALTH GOALS On Thursday, September 5, 2013, in the City of Lodi, Notice of Public Hearing to receive comments on and Report on Water Quality Relative to Public Health Exhibit A) was posted at the following locations: Lodi Public Library Lodi City Clerk's Office Lodi City Hall Lobby Lodi Carnegie Forum San Joaquin County, California, a consider accepting City of Lodi's Goals (attached and marked as I declare under penalty of perjury that the foregoing is true and correct. Executed on September 5, 2013, at Lodi, California. ASSISTANT CITY CLEVK N:\Administration\CLERK\Fonns\DECPOSTPW.DOC ORDERED BY: RANDI JOHL-OLSON CITY CLERK MARIA DITMORE ADMINISTRATIVE CLERK • CITY OF LODI Carnegie Forum • 305 West Pine Street, Lodi 14 NOTICE OF PUBLIC HEARING Date: October 2, 2013 Time: 7:00 p.m. For information regarding this notice please contact: Randi Johl-Olson, City Clerk Telephone: (209) 333-6702 NOTICE OF PUBLIC HEARING NOTICE IS HEREBY GIVEN that on Wednesday, October 2, 2013, at the hour of 7:00 p.m., or as soon thereafter as the matter may be heard, the City Council will conduct a public hearing at the Carnegie Forum, 305 West Pine Street, Lodi, to consider the following matter: a) Receive comments on and consider accepting City of Lodi's Report on Water Quality Relative to Public Health Goals. Information regarding this item may be obtained in the Public Works Department, 221 West Pine Street, Lodi, (209) 333-6706. All interested persons are invited to present their views and comments on this matter. Written statements may be filed with the City Clerk, City Hall, 221 West Pine Street, 2nd Floor, Lodi, 95240, at any time prior to the hearing scheduled herein, and oral statements may be made at said hearing. If you challenge the subject matter in court, you may be limited to raising only those issues you or someone else raised at the public hearing described in this notice or in written correspondence delivered to the City Clerk, 221 West Pine Street, at or prior to the close of the public hearing. B rd r of the Lodi City Council: R�a�- City Clerk Dated: September 4, 2013 Approved as to form: D. Stephen Schwabaue City Attorney N:\Administration\CLERK\PubHear\NOTICES\NotPW.doc CLERK\PUBHEAR\NOTICES\NotPW.doc 9/4/13